Benzhydryl phenyl sulfone

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Benzhydryl phenyl sulfone

In the title compound, C(19)H(16)O(2)S, the sulfur-bound phenyl group is approximately parallel to one of the two phenyl rings of the benzhydryl group, making a dihedral angle of 12.53 (10)°, and forms a dihedral angle of 41.25 (9)° with the other phenyl ring. In the crystal, weak C-H⋯O inter-actions form a two-dimensional network propagating along the bc plane.

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4,4′-Bis(dimethyl­amino)benzhydryl phenyl sulfone

In the title compound, C(23)H(26)N(2)O(2)S, the sulfur-bound phenyl group is aligned approximately parallel to one of the two rings of the benzhydryl group, making a dihedral angle of 1.15 (9)°. The other forms a dihedral angle of 59.20 (9)° with the phenyl group bound to the S atom. In the crystal, mol-ecules are linked into strands along [100] by weak C-H⋯O contacts. Weak C-H⋯π inter-actions ...

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3,5-Difluoro­phenyl phenyl sulfone

In the title compound, C(12)H(8)F(2)O(2)S, which is a precursor of functionalised poly(aryl-ene ether sulfone) polymers, the dihedral angle between the aromatic ring planes is 84.43 (8)°. In the crystal structure, aromatic π-π stacking [centroid-centroid separations = 3.808 (3) and 3.867 (3) Å] helps to establish the packing. A short C-H⋯F contact also occurs.

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(1R,3S)-N-Benzhydryl-2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carbothio­amide

The title compound, C(38)H(36)N(2)O(2)S, has a heterocyclic ring that assumes a half-chair conformation. The phenyl rings of neighbouring mol-ecules align forming alternating chains parallel to [100] within the crystal packing. The absolute stereochemistry of the crystal was confirmed to be R,S at the 1- and 3-positions, respectively, by proton NMR spectroscopy. A single intra-molecular N-H⋯N h...

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Derivatives of phenyl tribromomethyl sulfone as novel compounds with potential pesticidal activity

A halogenmethylsulfonyl moiety is incorporated in numerous active herbicides and fungicides. The synthesis of tribromomethyl phenyl sulfone derivatives as novel potential pesticides is reported. The title sulfone was obtained by following three different synthetic routes, starting from 4-chlorothiophenol or 4-halogenphenyl methyl sulfone. Products of its subsequent nitration were subjected to t...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809050363